A versatile synthesis of phosphine-aminophosphine ligands for asymmetric catalysis

被引：42

作者：

Boaz, NW ^{[1
]}

Ponasik, JA ^{[1
]}

Large, SE ^{[1
]}

机构：

[1] Eastman Chem Co, Res Labs, Kingsport, TN 37662 USA

来源：

TETRAHEDRON-ASYMMETRY | 2005年 / 16卷 / 12期

关键词：

D O I：

10.1016/j.tetasy.2005.05.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new and versatile synthesis of phosphine-aminophosphine ligands allows the incorporation of a wide range of nitrogen and phosphorus substituents into these ligands, several of which exhibit improved properties for rhodium-catalyzed asymmetric hydrogenation reactions. This synthesis also allows the preparation of mixed phosphine-phosphoramidite species. (c) 2005 Elsevier Ltd. All rights reserved.

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页码：2063 / 2066

页数：4

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