Highly selective hydrocarboxylation of styrene with oxalic acid or water using palladium ortho-amino arenethiolates with intramolecular coordinating nitrogen Lewis bases

被引：19

作者：

Kruis, D

Ruiz, N

Janssen, MD

Boersma, J

Claver, C

van Koten, G

机构：

[1] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Fac Quim, Tarragona 43005, Spain

[2] Univ Utrecht, Debye Inst, Dept Met Mediated Synth, NL-3584 CH Utrecht, Netherlands

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 08期

关键词：

hydrocarboxylation; palladium complexes; amino arenethiolate ligands; regioselectivity;

D O I：

10.1016/S1387-7003(98)00079-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Under mild conditions and in the presence of a catalytic amount of an S,N-chelated palladium ortho-amino arenethiolate complex, styrene reacts with carbon monoxide and oxalic acid or water to selectively give 2-phenylpropanoic acid in high yield. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：295 / 298

页数：4

共 24 条

[1] Catalytic hydrocarboxylation and hydroesterification reactions of 1,2-polybutadiene [J].