HIGHLY REGIOSELECTIVE IRON-PROMOTED HYDROCARBOXYLATION OF STYRENE

被引：10

作者：

BRUNET, JJ ^{[1
]}

NEIBECKER, D ^{[1
]}

SRIVASTAVA, RS ^{[1
]}

机构：

[1] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 17期

关键词：

D O I：

10.1016/S0040-4039(00)73555-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of Li[HFe(CO)4] with styrene under carbon monoxide (1 atm) in a H2O / iPrOH / LiOH system promotes a highly regioselective (98%) hydrocarboxylation to 2-phenylpropionic acid. In contrast, when conducted under argon, the reaction predominantly (90%) leads to 3-phenylpropionic acid.

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页码：2759 / 2762

页数：4

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