Anion-templated formation of a unique inorganic 'super-adamantoid' cage [Ag6(triphos)4(O3SCF3)4]2+ [triphos = (PPh2CH2)3CMe]

被引：89

作者：

James, SL ^{[1
]}

Mingos, DMP ^{[1
]}

White, AJP ^{[1
]}

Williams, DJ ^{[1
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 21期

关键词：

D O I：

10.1039/a806388e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of templating anions, 2:3 molar mixtures of triphos and silver(I) cations unexpectedly give novel hexanuclear cages, which result from an unusual 'endo-methyl' geometry of the triphos ligands.

引用

页码：2323 / 2324

页数：2

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