Spectrometric study of the size discrimination of quaternary ammonium cations by tetracyanoresorcin[4]arene

被引：7

作者：

Chen, WH ^{[1
]}

Wei, Y ^{[1
]}

Tan, SD ^{[1
]}

Wang, B ^{[1
]}

Xu, ZL ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

来源：

SUPRAMOLECULAR CHEMISTRY | 2005年 / 17卷 / 06期

关键词：

resorcin[4]arene; quaternary ammonium; recognition; spectrometry;

D O I：

10.1080/10610270500211818

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The inclusion complexes of tetracyanoresorcin[4]arene with six quaternary ammonium cations-biologically important acetylcholine and choline, tetramethyl ammonium, tetraethyl ammonium, tetrapropyl ammonium and tetrabutyl ammonium-were studied by means of electrospray ionization mass, fluorescence and NMR spectrometries. The results indicate that tetracyanoresorcin[4]arene shows high affinity toward these ammoniums and is capable of recognizing their sizes.

引用

页码：469 / 473

页数：5

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