Triazole- and triazolium-containing porphyrin-cages for optical anion sensing

被引：70

作者：

Gilday, Lydia C. ^{[1
]}

White, Nicholas G. ^{[1
]}

Beer, Paul D. ^{[1
]}

机构：

[1] Univ Oxford, Inorgan Chem Lab, Dept Chem, Oxford OX1 3QR, England

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 23期

基金：

英国工程与自然科学研究理事会;

关键词：

COMPUTER-PROGRAM; CLICK CHEMISTRY; RECOGNITION; RECEPTORS; BINDING; SENSORS; TETRAPHENYLPORPHINATOZINC; CONSTANTS; ROTAXANES; LIGANDS;

D O I：

10.1039/c2dt30124e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Triazole and triazolium groups have been integrated into a zinc(II) metalloporphyrin-based structural framework to produce two porphyrin-cages for anion sensing applications. UV/visible spectroscopic titration investigations reveal both host systems exhibit strong anion binding affinities, with the positively-charged triazolium-porphyrin cage capable of colorimetric sensing halides, fluoride and chloride, and oxoanions in acetone-water solvent mixtures.

引用

页码：7092 / 7097

页数：6

共 42 条

[1] A SIMPLIFIED SYNTHESIS FOR MESO-TETRAPHENYLPORPHIN [J].

ADLER, AD ;

LONGO, FR ;

FINARELLI, JD ;

GOLDMACH.J ;

ASSOUR, J ;

KORSAKOF.L .

JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (02) :476-+

[2]

[Anonymous], CRYSALIS PRO

[3]

[Anonymous], SPECF V 2 02

[4]

[Anonymous], 1997, SUPRAMOLECULAR CHEM

[5] CONCERNING MESO-TETRAPHENYLPORPHYRIN PURIFICATION [J].

BARNETT, GH ;

HUDSON, MF ;

SMITH, KM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1975, (14) :1401-1403

[6] Selective anion recognition by novel 5,10,15,20-tetrakis(o-ferrocenyl-carbonylaminophenyl-substituted) zinc metalloporphyrin receptors [J].

Beer, PD ;

Drew, MGB ;

Jagessar, R .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (05) :881-886

[7] Zinc metalloporphyrin-functionalised nanoparticle anion sensors [J].

Beer, PD ;

Cormode, DP ;

Davis, JJ .

CHEMICAL COMMUNICATIONS, 2004, (04) :414-415

[8] CRYSTALS version 12: software for guided crystal structure analysis [J].

Betteridge, PW ;

Carruthers, JR ;

Cooper, RI ;

Prout, K ;

Watkin, DJ .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2003, 36 :1487-1487

[9] CuI-catalyzed alkyne-azide "click" cycloadditions from a mechanistic and synthetic perspective [J].

Bock, VD ;

Hiemstra, H ;

van Maarseveen, JH .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 2006 (01) :51-68

[10] SYNTHESES OF QUADRUPLY 2-ATOM AND 3-ATOM, AZA-BRIDGED, COFACIAL BIS(5,10,15,20-TETRAPHENYLPORPHYRINS) [J].

BOOKSER, BC ;

BRUICE, TC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (11) :4208-4218

← 1 2 3 4 5 →