Coordination copolymerization of polar vinyl monomers H2C=CHX

被引：175

作者：

Berkefeld, Andreas ^{[1
]}

Mecking, Stefan ^{[1
]}

机构：

[1] Univ Konstanz, Fachbereich Chem, Lehrstuhl Chem Mat Wissensch, D-78457 Constance, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 14期

关键词：

copolymerization; homogeneous catalysis; palladium; polymers; polyolefins;

D O I：

10.1002/anie.200704642

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Rising to the challenge: Neutral phosphinosulfonate PdII complexes were recently demonstrated to be versatile catalysts even for the challenging insertion copolymerization of polar functionalized vinyl comonomers H2C=CHX, such as acrylonitrile, vinyl acetate, and alkyl vinyl ethers (see scheme, MA = methyl acrylate). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2538 / 2542

页数：5

共 65 条

[1]

[Anonymous], ZIEGLER CATALYSTS

[2]

Bauers F. M., 2001, ANGEW CHEM, V113, P3112

[3]

Bauers FM, 2001, ANGEW CHEM INT EDIT, V40, P3020, DOI 10.1002/1521-3773(20010817)40:16<3020::AID-ANIE3020>3.0.CO

[4]

2-7

[5] Copolymerization of polar monomers with olefins using transition-metal complexes [J].

Boffa, LS ;

Novak, BM .

CHEMICAL REVIEWS, 2000, 100 (04) :1479-1493

[6] Copolymerization studies of vinyl chloride and vinyl acetate with ethylene using a transition-metal catalyst [J].

Boone, HW ;

Athey, PS ;

Mullins, MJ ;

Philipp, D ;

Muller, R ;

Goddard, WA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (30) :8790-8791

[7]

Braunstein P, 2000, ANGEW CHEM INT EDIT, V39, P2867, DOI 10.1002/1521-3773(20000818)39:16<2867::AID-ANIE2867>3.0.CO

[8]

2-X

[9]

Braunstein P., 2000, ANGEW CHEM, V112, P2989

[10] HEMILABILE P,O-LIGANDS IN PALLADIUM-CATALYZED C-C LINKAGES - CODIMERIZATION OF ETHYLENE AND STYRENE AND COOLIGOMERIZATION OF ETHYLENE AND CARBON-MONOXIDE [J].

BRITOVSEK, GJP ;

KEIM, W ;

MECKING, S ;

SAINZ, D ;

WAGNER, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (21) :1632-1634

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