Coordination copolymerization of polar vinyl monomers H2C=CHX

被引：175

作者：

Berkefeld, Andreas ^{[1
]}

Mecking, Stefan ^{[1
]}

机构：

[1] Univ Konstanz, Fachbereich Chem, Lehrstuhl Chem Mat Wissensch, D-78457 Constance, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 14期

关键词：

copolymerization; homogeneous catalysis; palladium; polymers; polyolefins;

D O I：

10.1002/anie.200704642

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Rising to the challenge: Neutral phosphinosulfonate PdII complexes were recently demonstrated to be versatile catalysts even for the challenging insertion copolymerization of polar functionalized vinyl comonomers H2C=CHX, such as acrylonitrile, vinyl acetate, and alkyl vinyl ethers (see scheme, MA = methyl acrylate). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2538 / 2542

页数：5

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