ANION-CONTROLLED OLIGOMERIZATION OF CARBON-MONOXIDE AND NORBORNENE ON A PALLADIUM(II) CENTER

被引：48

作者：

MARKIES, BA

VERKERK, KAN

RIETVELD, MHP

BOERSMA, J

KOOIJMAN, H

SPEK, AL

VANKOTEN, G

机构：

[1] UNIV UTRECHT,DEPT MET MEDIATED SYNTH,DEBYE INST,PADUALAAN 8,3584 CH UTRECHT,NETHERLANDS

[2] UNIV UTRECHT,CRYSTAL & STRUCT CHEM LAB,BIJVOET CTR BIOMOLEC RES,3584 CH UTRECHT,NETHERLANDS

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 17期

关键词：

D O I：

10.1039/c39930001317

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The insertion of both norbornene and carbon monoxide into the Pd-C bond of 2,2'-bipyridyl coordinated palladium(II) complexes can be controlled by the nature of the anions present in solution, and this allows the stepwise synthesis of a metal-bound CO/norbornene co-oligomer of which an X-ray crystal structure is presented.

引用

页码：1317 / 1319

页数：3

共 15 条

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