On the synthesis of monovalent, divalent, and trivalent element vanadates

被引：45

作者：

Baudrin, E ^{[1
]}

Denis, S ^{[1
]}

Orsini, F ^{[1
]}

Seguin, L ^{[1
]}

Touboul, M ^{[1
]}

Tarascon, JM ^{[1
]}

机构：

[1] Univ Picardie Jules Verne, Lab React & Chim Solides, F-80039 Amiens, France

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1999年 / 9卷 / 01期

关键词：

D O I：

10.1039/a805662e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A chimie douce method has been used to prepare vanadates (V5+) of various elements, trivalent (Al, Cr, Fe, In, Y, Bi), divalent (Co, Ni), monovalent (Li, Tl), and a combination of nickel and lithium. By varying several parameters, especially the pH during the synthesis, several types of vanadates have been obtained ranging from orthovanadates (VO43-) to decavanadates (V10O286-). The pH conditions required to prepare the various vanadates fall nicely within the expectations of the previously reported cation charge-pH diagram.

引用

页码：101 / 105

页数：5

共 27 条

[1]

Baudrin E, 1997, EUR J SOL STATE INOR, V34, P1011

[2]

BAUDRIN E, UNPUB

[3] Synthesis and electrochemical properties of amorphous vanadates of general formula RVO4 (R = In, Cr, Fe, Al, Y) vs. Li [J].

Denis, S ;

Baudrin, E ;

Touboul, M ;

Tarascon, JM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (12) :4099-4109

[4]

DENIS S, 1998, THESIS AMIENS

[5]

DENIS S, 1994, DEA SPECTROCHIMIE

[6]

DERAEDT K, 1993, DEA SPECTROCHIMIE

[7] A SIMPLIFIED CRITERION FOR RELIABILITY OF A POWDER PATTERN INDEXING [J].

DEWOLFF, PM .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1968, 1 :108-+

[8] STRUCTURE AND MAGNETIC-PROPERTIES OF LIMVO4 (M=CO, NI, CU) SPINELS [J].

GONZALEZ, C ;

GAITAN, M ;

LOPEZ, ML ;

VEIGA, ML ;

SAEZPUCHE, R ;

PICO, C .

JOURNAL OF MATERIALS SCIENCE, 1994, 29 (13) :3458-3460

[9]

Idota Y., 1993, Eur. Pat., Patent No. [0 567 149 A1, 0567149]

[10]

JOLIVET J, 1994, SOLUTION OXYDE

← 1 2 3 →