On the synthesis of monovalent, divalent, and trivalent element vanadates

被引：45

作者：

Baudrin, E ^{[1
]}

Denis, S ^{[1
]}

Orsini, F ^{[1
]}

Seguin, L ^{[1
]}

Touboul, M ^{[1
]}

Tarascon, JM ^{[1
]}

机构：

[1] Univ Picardie Jules Verne, Lab React & Chim Solides, F-80039 Amiens, France

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1999年 / 9卷 / 01期

关键词：

D O I：

10.1039/a805662e

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A chimie douce method has been used to prepare vanadates (V5+) of various elements, trivalent (Al, Cr, Fe, In, Y, Bi), divalent (Co, Ni), monovalent (Li, Tl), and a combination of nickel and lithium. By varying several parameters, especially the pH during the synthesis, several types of vanadates have been obtained ranging from orthovanadates (VO43-) to decavanadates (V10O286-). The pH conditions required to prepare the various vanadates fall nicely within the expectations of the previously reported cation charge-pH diagram.

引用

页码：101 / 105

页数：5

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