The fabrication and characterization of inkjet-printed polyaniline nanoparticle films

被引:75
作者
Morrin, Aoife [1 ]
Ngamna, Orawan [3 ]
O'Malley, Eimer [1 ]
Kent, Nigel [2 ]
Moulton, Simon E. [3 ]
Wallace, Gordon G. [3 ]
Smyth, Malcolm R. [1 ]
Killard, Anthony J. [1 ]
机构
[1] Dublin City Univ, Sch Chem Sci, Natl Ctr Sensor Res, Dublin 9, Ireland
[2] Dublin City Univ, Natl Ctr Sensor Res, Sch Mech & Mfg Engn, Dublin 9, Ireland
[3] Univ Wollongong, Intelligent Polymer Res Inst, ARC Ctr Excellence Electromat Sci, Wollongong, NSW 2522, Australia
基金
澳大利亚研究理事会;
关键词
inkjet printing; polyaniline; nanoparticles; screen-printed electrodes; sensor;
D O I
10.1016/j.electacta.2008.02.010
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
This paper reports on the fabrication and characterization of electrodes modified with conducting polymer nanoparticle films, produced via inkjet printing. The polyaniline nanoparticle formulations were deposited via a desktop inkjet printer onto screen-printed carbon-paste electrodes (SPE), polyethylene terephthalate (PET) and gold-PET and their morphology studied at a range of length scales using profilometry, scanning electron microscopy and atomic force microscopy. The deposited films were found to form continuous polymer films depending upon film thickness, which was in turn dependent on the number of prints performed. The inkjet-printed films exhibited a smooth morphology on the SPEs at the micro-dimensional scale, as a result of the aggradation and coalescing of the nanoparticles upon deposition. The resulting modified electrodes were both conductive and electroactive, possessing good reversible polyaniline electrochemistry. Such a combination of materials and processing offers the potential of producing a range of low cost, solid state devices such as sensors, actuators and electrochromic devices. (C) 2008 Elsevier Ltd. All fights reserved.
引用
收藏
页码:5092 / 5099
页数:8
相关论文
共 33 条
[1]   Thermal inkjet microdeposition of PEDOT:PSS on ITO-coated glass and characterization of the obtained film [J].
Ballarin, B ;
Fraleoni-Morgera, A ;
Frascaro, D ;
Marazzita, S ;
Piana, C ;
Setti, L .
SYNTHETIC METALS, 2004, 146 (02) :201-205
[2]   Inkjet printing for materials and devices [J].
Calvert, P .
CHEMISTRY OF MATERIALS, 2001, 13 (10) :3299-3305
[3]   Fabricating optical fiber imaging sensors using inkjet printing technology: A pH sensor proof-of-concept [J].
Carter, JC ;
Alvis, RM ;
Brown, SB ;
Langry, KC ;
Wilson, TS ;
McBride, MT ;
Myrick, ML ;
Cox, WR ;
Grove, ME ;
Colston, BW .
BIOSENSORS & BIOELECTRONICS, 2006, 21 (07) :1359-1364
[4]   All-polymer RC filter circuits fabricated with inkjet printing technology [J].
Chen, B ;
Cui, TH ;
Liu, Y ;
Varahramyan, K .
SOLID-STATE ELECTRONICS, 2003, 47 (05) :841-847
[5]   Negative capacitance for polyaniline: an analysis via electrochemical impedance spectroscopy [J].
Chen, WC ;
Wen, TC ;
Gopalan, A .
SYNTHETIC METALS, 2002, 128 (02) :179-189
[6]  
FERRARIS JP, 2002, Patent No. 6501587
[7]   Highly efficient photovoltaic cells composed of interpenetrating conducting polymer/C60 heterojunction [J].
Fujii, A ;
Mizukami, H ;
Hashimoto, Y ;
Umeda, T ;
Nishihara, Y ;
Ozaki, A ;
Yoshino, K .
SYNTHETIC METALS, 2005, 152 (1-3) :121-124
[8]  
FUKUSHIMA H, 2004, Patent No. 6762050
[9]  
Grennan K, 2001, ELECTROANAL, V13, P745, DOI 10.1002/1521-4109(200105)13:8/9<745::AID-ELAN745>3.0.CO
[10]  
2-B