Improvement of thermal and mechanical properties of carbon nanotube composites through chemical functionalization

被引:311
作者
Velasco-Santos, C
Martínez-Hernández, AL
Fisher, FT
Ruoff, R
Castaño, VM
机构
[1] Univ Nacl Autonoma Mexico, Ctr Fis Aplicada & Tecnol Avanzada, Santiago De Queretaro 76000, Queretaro, Mexico
[2] Univ Autonoma Queretaro, Santiago De Queretaro 76010, Queretaro, Mexico
[3] Northwestern Univ, Dept Mech Engn, Evanston, IL 60208 USA
关键词
D O I
10.1021/cm034243c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Chemically functionalized multiwalled carbon nanotubes were incorporated into a polymer matrix by in situ polymerization, to improve the transfer of mechanical load through a chemical bond, which was demonstrated by Raman and infrared spectroseopies. The resulting composite shows higher storage modulus (E) and tensile strength than existing similar composites, with only 1 wt % of functionalized nanotubes. E' at 90 degreesC is increased by an outstanding 1135% and the glass transition temperature is exceptionally raised by congruent to40 degreesC.
引用
收藏
页码:4470 / 4475
页数:6
相关论文
共 38 条
[21]   Enhancement of adsorption inside of single-walled nanotubes: opening the entry ports [J].
Kuznetsova, A ;
Mawhinney, DB ;
Naumenko, V ;
Yates, JT ;
Liu, J ;
Smalley, RE .
CHEMICAL PHYSICS LETTERS, 2000, 321 (3-4) :292-296
[22]  
LONG DA, 1997, RAMAN SPECTROSCOPY
[23]   Evaluation of Young's modulus of carbon nanotubes by micro-Raman spectroscopy [J].
Lourie, O ;
Wagner, HD .
JOURNAL OF MATERIALS RESEARCH, 1998, 13 (09) :2418-2422
[24]   Buckling and collapse of embedded carbon nanotubes [J].
Lourie, O ;
Cox, DM ;
Wagner, HD .
PHYSICAL REVIEW LETTERS, 1998, 81 (08) :1638-1641
[25]   Two-dimensional Fourier-transform Raman and near-infrared correlation spectroscopy studies of poly (methyl methacrylate) blends 1. Immiscible blends of poly(methyl methacrylate) and atactic polystyrene [J].
Matsushita, A ;
Ren, YZ ;
Matsukawa, K ;
Inoue, H ;
Minami, Y ;
Noda, I ;
Ozaki, Y .
VIBRATIONAL SPECTROSCOPY, 2000, 24 (02) :171-180
[26]  
Menard KP, 1999, DYNAMIC MECH ANAL
[27]  
MENARD KP, 2000, PERFORMANCE PLASTICS, pCH8
[28]   Chemical functionalization of carbon nanotubes through energetic radical collisions [J].
Ni, B ;
Sinnott, SB .
PHYSICAL REVIEW B, 2000, 61 (24) :16343-16346
[29]   Load transfer and deformation mechanisms in carbon nanotube-polystyrene composites [J].
Qian, D ;
Dickey, EC ;
Andrews, R ;
Rantell, T .
APPLIED PHYSICS LETTERS, 2000, 76 (20) :2868-2870
[30]  
ROEGES NPG, 1997, GUIDE COMPLETE INTER