The shear-induced transition between oriented textures and layer-sliding-mediated flows in a micellar cubic crystal

被引:36
作者
Berret, JF
Molino, F
Porte, G
Diat, O
Lindner, P
机构
[1] EUROPEAN SYNCHROTRON RADIAT FACIL,F-38042 GRENOBLE,FRANCE
[2] INST MAX VON LAUE PAUL LANGEVIN,F-38042 GRENOBLE 9,FRANCE
关键词
D O I
10.1088/0953-8984/8/47/054
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
A series of experiments has been performed in order to analyse the shear-induced structures for a micellar cubic phase using small-angle neutron and x-ray scattering techniques. Steady shear was applied in a Couette cell to the (EO)(127)(PO)(48)(EO)(127) triblock copolymer system dissolved in water. At rest, the system crystallizes into a long-range ordered mesophase of face-centred symmetry (lattice parameter similar to 300 Angstrom). The good resolution of the x-ray technique enables us to study in detail the transition between shearing flows dominated by oriented textures at law shear rates (gamma < 1 s(-1)) and flows mediated by the mechanisms of layer sliding at higher rates (gamma > 100 s(-1)).
引用
收藏
页码:9513 / 9517
页数:5
相关论文
共 11 条
[1]   SHEAR-INDUCED MELTING [J].
ACKERSON, BJ ;
CLARK, NA .
PHYSICAL REVIEW LETTERS, 1981, 46 (02) :123-126
[2]  
ACKERSON BJ, 1987, PHYSICS COMPLEX SUPE, P553
[3]   HIGH-BRILLIANCE BEAMLINE AT THE EUROPEAN SYNCHROTRON-RADIATION FACILITY [J].
BOSECKE, P ;
DIAT, O ;
RASMUSSEN, B .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1995, 66 (02) :1636-1638
[4]  
DIAT O, 1996, PHYS REV B, V54
[5]   DISCONTINUOUS AND DILATANT VISCOSITY BEHAVIOR IN CONCENTRATED SUSPENSIONS .1. OBSERVATION OF A FLOW INSTABILITY [J].
HOFFMAN, RL .
TRANSACTIONS OF THE SOCIETY OF RHEOLOGY, 1972, 16 (01) :155-&
[6]   MODEL-CALCULATIONS FOR THE ANALYSIS OF SCATTERING DATA FROM LAYERED STRUCTURES [J].
LOOSE, W ;
ACKERSON, BJ .
JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (09) :7211-7220
[7]   DISORDER-ORDER TRANSITIONS IN SOFT-SPHERE POLYMER MICELLES [J].
MCCONNELL, GA ;
GAST, AP ;
HUANG, JS ;
SMITH, SD .
PHYSICAL REVIEW LETTERS, 1993, 71 (13) :2102-2105
[8]   LONG-RANGE ORDER IN POLYMERIC MICELLES UNDER STEADY SHEAR [J].
MCCONNELL, GA ;
LIN, MY ;
GAST, AP .
MACROMOLECULES, 1995, 28 (20) :6754-6764
[9]   INVERSE MELTING TRANSITION AND EVIDENCE OF 3-DIMENSIONAL CUBATIC STRUCTURE IN A BLOCK-COPOLYMER MICELLAR SYSTEM [J].
MORTENSEN, K ;
BROWN, W ;
NORDEN, B .
PHYSICAL REVIEW LETTERS, 1992, 68 (15) :2340-2343
[10]   SHEAR DEVICES FOR IN-SITU STRUCTURAL STUDIES OF BLOCK-COPOLYMER MELTS AND SOLUTIONS [J].
MORTENSEN, K ;
ALMDAL, K ;
BATES, FS ;
KOPPI, K ;
TIRRELL, M ;
NORDEN, B .
PHYSICA B, 1995, 213 :682-684