学术探索
学术期刊
新闻热点
数据分析
智能评审

The influence of the monomer and the ionic liquid on the electrochemical preparation of polythiophene

被引：128
作者：
Pringle, JM
Forsyth, M
MacFarlane, DR
Wagner, K
Hall, SB
Officer, DL
机构：
[1] Monash Univ, Sch Phys & Mat Engn, Clayton, Vic 3800, Australia
[2] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
[3] Massey Univ, Nanomat Res Ctr, Palmerston North, New Zealand
[4] Massey Univ, MacDiarmid Inst Adv Mat & Nanotechnol, Palmerston North, New Zealand
来源：
POLYMER | 2005年 / 46卷 / 07期
基金：
澳大利亚研究理事会;
关键词：
thiophene; ionic-liquids; electropolymerisation;
D O I：
10.1016/j.polymer.2005.01.034
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Thiophene, bithiophene and terthiophene have been electropolymerised using ionic liquids as the growth medium and the supporting electrolyte. Both imidazolium and pyrrolidinium-based ionic liquids were used to assess the influence of the nature of the ionic liquid on the morphology and electrochemical activity of the conducting polymers. The pyrrolidinium-based ionic liquid produced slightly smoother films for all the thiophene species studied. A number of the polymers displayed multiple redox peaks, the possible origins of which are discussed. Both the ionic liquid and the choice of monomer had a significant influence on the polymer produced. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2047 / 2058
页数：12
相关论文
共 75 条
[21]   FORMATION AND ELECTROCHEMISTRY OF POLYFLUORENE IN AMBIENT-TEMPERATURE IONIC LIQUIDS [J].
JANISZEWSKA, L ;
OSTERYOUNG, RA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1988, 135 (01) :116-122
[22]   ELECTROCHEMISTRY OF POLYTHIOPHENE AND POLYBITHIOPHENE FILMS IN AMBIENT-TEMPERATURE MOLTEN-SALTS [J].
JANISZEWSKA, L ;
OSTERYOUNG, RA .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (11) :2787-2794
[23]   Physical characterization of electrochemically and chemically synthesized polypyrroles [J].
Joo, J ;
Lee, JK ;
Lee, SY ;
Jsng, KS ;
Oh, EJ ;
Epstein, AJ .
MACROMOLECULES, 2000, 33 (14) :5131-5136
[24]  
KRISCHE B, 1989, SYNTHETIC MET, V28, pC263
[25]  
Lee KH, 1998, ADV MATER, V10, P456, DOI 10.1002/(SICI)1521-4095(199804)10:6<456::AID-ADMA456>3.0.CO
[26]  
2-M
[27]   ELECTROCHEMICAL DEPOSITION OF A CONDUCTING POLYMER, POLY(THIOPHENE-3-ACETIC ACID) - THE 1ST OBSERVATION OF INDIVIDUAL EVENTS OF POLYMER NUCLEATION AND 2-DIMENSIONAL LAYER-BY-LAYER GROWTH [J].
LI, FB ;
ALBERY, WJ .
LANGMUIR, 1992, 8 (06) :1645-1653
[28]   Use of ionic liquids for π-conjugated polymer electrochemical devices [J].
Lu, W ;
Fadeev, AG ;
Qi, BH ;
Smela, E ;
Mattes, BR ;
Ding, J ;
Spinks, GM ;
Mazurkiewicz, J ;
Zhou, DZ ;
Wallace, GG ;
MacFarlane, DR ;
Forsyth, SA ;
Forsyth, M .
SCIENCE, 2002, 297 (5583) :983-987
[29]   Fabricating conducting polymer electrochromic devices using ionic liquids [J].
Lu, W ;
Fadeev, AG ;
Qi, BH ;
Mattes, BR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (02) :H33-H39
[30]   Stable conducting polymer electrochemical devices incorporating ionic liquids [J].
Lu, W ;
Fadeev, AG ;
Qi, B ;
Mattes, BR .
SYNTHETIC METALS, 2003, 135 (1-3) :139-140
12345678