Synthesis of unsymmetric ketones via ligandless Pd-catalyzed reaction of acyl chlorides with organoboranes

被引：135

作者：

Bumagin, NA ^{[1
]}

Korolev, DN ^{[1
]}

机构：

[1] Moscow State Univ, Dept Chem, Moscow 119899, Russia

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 15期

关键词：

D O I：

10.1016/S0040-4039(99)00364-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cross-coupling reaction of sodium tetra-arylborates with acyl chlorides to give high yields of unsymmetric ketones has been carried out at 20 degrees C in the presence of Pd(OAc)(2) and Na2CO3 in dry or aqueous acetone. Under aqueous conditions arylboronic acids react smoothly with benzoyl chloride resulting in substituted benzophenones. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：3057 / 3060

页数：4