Cyclopentadienyl derivatives of aluminum (I)

被引：66

作者：

Sitzmann, H

Lappert, MF

Dohmeier, C

Uffing, C

Schnockel, H

机构：

[1] Univ Karlsruhe, Inst Anorgan Chem, D-76128 Karlsruhe, Germany

[2] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

[3] Univ Kaiserslautern, Fachbereich Chem Univ, D-67663 Kaiserslautern, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 561卷 / 1-2期

关键词：

Al-27-NMR spectroscopy; x-ray structure; Al(I) compounds; Cp derivatives of aluminum; quantum chemical calculations;

D O I：

10.1016/S0022-328X(98)00555-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Al-27-NMR spectroscopy to investigate and characterize new cyclopentadienylaluminum(I) derivatives formed in the reaction of AlX (X = Cl, Br, Cp* (= C5Me5)) with MRn (n = 1: M = alkaline metal; n = 2: M = Mg; R = cyclopentadienyl derivative (Cp-D), N(SiMe3)(2)): formation of new monomeric and tetrameric Al(I) species and X-ray structure analysis of a new aluminum(I) compound with an Al-4-tetrahedron. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：203 / 208

页数：6

共 18 条

[1] ELECTRONIC-STRUCTURE CALCULATIONS ON WORKSTATION COMPUTERS - THE PROGRAM SYSTEM TURBOMOLE [J].