Fatty acid composition of some seed oils of the sapindaceae

被引：31

作者：

Spitzer, V

机构：

[1] Faculdade de Farmácia UFRGS, Curso de Pos-Graduação, 90610.000 Porto Alegre/RS, Avenida Ipiranga

来源：

PHYTOCHEMISTRY | 1996年 / 42卷 / 05期

关键词：

Paullina meliaefolia; Urvillea uniloba; Cardiospermum grandiflorum; Sapindaceae; seed oils; eicosenoic fatty acids; paullinic acid; cyanolipids; GC-MS;

D O I：

10.1016/0031-9422(96)00140-9

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The fatty acid compositions of the seed oils of Paullina meliaefolia, Urvillea uniloba and Cardiospermum grandiforum have been analysed as their methyl esters and 4,4-dimethyloxazoline derivatives by GC and GC-mass spectrometry. cis-13-Eicosenoic Acid (paullinic acid) and cis-11-octadecenoic acid (cis-vaccenic acid) were found to be the main components besides other monoenoic acid positional isomers. The stereochemistry of the double bonds was confirmed by IR and C-13 NMR spectroscopy. Moreover, the unusual fatty acids C16:2(c9, c12) and C20:2 (c11, c14) have been detected as minor compounds. The cyanolipids were identified as 1-cyano-2-hydroxymethylprop-2-ene-1-ol and 1-cyano-2-hydroxymethylprop-1-ene-3-ol derivatives by spectroscopic methods.

引用

页码：1357 / 1360

页数：4

共 30 条

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[12] EICOSENOIC ACID AND OTHER FATTY ACIDS OF SAPINDACEAE SEED OILS [J].