Reactions of alkyl-iron(II) and -ruthenium(II) complexes with B(C6F5)3 and its water adducts.: X-ray structure of a cyclometallated-iron(II) carbene

被引：10

作者：

Bellachioma, G

Cardaci, G

Foresti, E

Macchioni, A

Sabatino, P

Zuccaccia, C

机构：

[1] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy

[2] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

INORGANICA CHIMICA ACTA | 2003年 / 353卷

关键词：

cyclometallated-iron(II) carbene; B(C6F5)(3) activation; B(C6F5)(3)center dot H2O reactivity;

D O I：

10.1016/S0020-1693(03)00327-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of cis,trans-[M(CO)(2)(PMe3)(2)CH3I] [M = Fe (1), Ru (2)] and cis,traps,cis-[Fe(CO)(2)(PMe3)(2)(CH3)(2)] (3) with B(C6F5)(3) involve Me-abstraction from the metal with formation of reactive species that undergo decomposition processes. In the presence of H2O complex 2 reacts with B(C6F5)(3) forming cis,trans-[Ru(CO)(2)(PMe3)(2)I(HOB(C6F5)(3))] (7) that slowly transforms in cis,trans-[Ru(CO)(2)(PMe3)(2)I(H2O)](+)[(HOB(C6F5)(3))](-) (8), while complex 1 affords the cyclometallate complex trans[Fe(CO)(PMe3)(2)I(=C(Me)-O-B(C6F5)(2)-OH-)] (9) whose molecular structure was investigated by X-ray diffraction studies. (C) 2003 Elsevier B.V. All rights reserved.

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页码：245 / 252

页数：8

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