Metal-organic complex ferroelectrics

被引：310

作者：

Hang, Tian ^{[1
]}

Zhang, Wen ^{[1
]}

Ye, Heng-Yun ^{[1
]}

Xiong, Ren-Gen ^{[1
]}

机构：

[1] Southeast Univ, Ordered Matter Sci Res Ctr, Nanjing 211189, Peoples R China

来源：

CHEMICAL SOCIETY REVIEWS | 2011年 / 40卷 / 07期

关键词：

PHASE-TRANSITIONS; DIELECTRIC-PROPERTIES; CRYSTAL;

D O I：

10.1039/c0cs00226g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ferroelectric materials are of importance and interest in both fundamental scientific research and various technological applications. Metal-organic complexes (MOCs) represent a class of molecule-based ferroelectrics, which have shown various properties or functionalities due to their hybrid inorganic-organic nature. This tutorial review shows the recent development of the MOC ferroelectrics with particular emphases on the mechanism of ferroelectric-to-paraelectric phase transition, symmetry consideration, and multifunctionality.

引用

页码：3577 / 3598

页数：22

共 54 条

[1] POSSIBLE SPECIES OF FERROMAGNETIC, FERROELECTRIC, AND FERROELASTIC CRYSTALS [J].

AIZU, K .

PHYSICAL REVIEW B, 1970, 2 (03) :754-&

[2]

Akutagawa T, 2009, NAT MATER, V8, P342, DOI [10.1038/NMAT2377, 10.1038/nmat2377]

[3] DIELECTRIC-DISPERSION IN FERROELECTRICS [NH2(CH3)2]3SB2CL9 AND [NH2(CH3)2]3SB2BR9 [J].

BATOR, G ;

JAKUBAS, R .

PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1995, 147 (02) :591-600

[4] Aminoguanidinium hexafluorozirconate: a new ferroelectric [J].

Bauer, MR ;

Pugmire, DL ;

Paulsen, BL ;

Christie, RJ ;

Arbogast, DJ ;

Gallagher, CS ;

Raveane, WV ;

Nielson, RM ;

Ross, CR ;

Photinos, P ;

Abrahams, SC .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2001, 34 :47-54

[5] On structural phase transitions in piperidinium halogenoantimonates(III) and bismuthates(III): X-ray, calorimetric, dilatometric, dielectric and Raman studies [J].

Bednarska-Bolek, B ;

Zaleski, J ;

Bator, G ;

Jakubas, R .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2000, 61 (08) :1249-1261

[6] Thermally Induced Bi(III) Lone Pair Stereoactivity: Ferroelectric Phase Transition and Semiconducting Properties of (MV)BiBr5 (MV = methylviologen) [J].

Bi, Wenhua ;

Leblanc, Nicolas ;

Mercier, Nicolas ;

Auban-Senzier, Pascale ;

Pasquier, Claude .

CHEMISTRY OF MATERIALS, 2009, 21 (18) :4099-4101

[7] Dielectric properties of porous molecular crystals that contain polar molecules [J].

Cui, HB ;

Takahashi, K ;

Kano, Y ;

Kobayashi, H ;

Wang, ZM ;

Kobayashi, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (40) :6508-6512

[8] Ferroelectric porous molecular crystal, [Mn3(HCOO)6](C2H5OH), exhibiting ferrimagnetic transition [J].

Cui, HengBo ;

Wang, Zheming ;

Takahashi, Kazuyuki ;

Okano, Yoshinori ;

Kobayashi, Hayao ;

Kobayashi, Akiko .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (47) :15074-15075

[9] FERROELECTRIC PHASE-TRANSITION IN METHYLAMMONIUM TETRACHLOROALUMINATE CRYSTALS [J].

CZAPLA, Z ;

CZUPINSKI, O ;

CIUNIK, Z .

SOLID STATE COMMUNICATIONS, 1986, 58 (06) :383-384

[10] Multiferroic and magnetoelectric materials [J].

Eerenstein, W. ;

Mathur, N. D. ;

Scott, J. F. .

NATURE, 2006, 442 (7104) :759-765

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