Catalytic enone cycloallylation via concomitant activation of latent nucleophilic and electrophilic partners: Merging organic and transition metal catalysis

被引：209

作者：

Jellerichs, BG ^{[1
]}

Kong, JR ^{[1
]}

Krische, MJ ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 26期

关键词：

D O I：

10.1021/ja0301469

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Upon exposure of mono-enone mono-allylic carbonates to tributylphosphine and 1 mol % Pd(Ph3P)4, efficient conversion to the corresponding cycloallylated products is achieved. This transformation combines the nucleophilic features of the Morita-Baylis-Hillman reaction with the electrophilic features of the Trost-Tsuji reaction. Copyright © 2003 American Chemical Society.

引用

页码：7758 / 7759

页数：2

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