Expanding the Scope of Metal-Free Catalytic Hydrogenation through Frustrated Lewis Pair Design

被引：207

作者：

Eros, Gabor ^{[1
]}

Mehdi, Hasan ^{[1
]}

Papai, Imre ^{[2
]}

Rokob, Tibor Andras ^{[2
]}

Kiraly, Peter ^{[2
]}

Tarkanyi, Gabor ^{[2
]}

Soos, Tibor ^{[1
]}

机构：

[1] Hungarian Acad Sci, Inst Biomol Chem, Chem Res Ctr, H-1525 Budapest, Hungary

[2] Hungarian Acad Sci, Inst Struct Chem, Chem Res Ctr, H-1525 Budapest, Hungary

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 37期

关键词：

amines; boranes; catalytic hydrogenation; frustrated Lewis pairs; hydrogen activation; HETEROLYTIC DIHYDROGEN ACTIVATION; H-2; ACTIVATION; MECHANISM; ACID; REACTIVITY; IMINES; BORANE; B(C6F5)(3); PHOSPHINES; REDUCTION;

D O I：

10.1002/anie.201001518

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

No metal causes frustration: Based on a conceptual framework, novel frustrated Lewis acid-base catalyst systems with orthogonal reactivity have been developed. Aside from enhanced functional-group tolerance, unique chemoselectivity can be achieved in catalytic metal-free hydrogenations (see scheme). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6559 / 6563

页数：5

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