Dihydrogen reduction of carboxylic esters to alcohols under the catalysis of homogeneous ruthenium complexes: High efficiency and unprecedented chemoselectivity

被引：204

作者：

Saudan, Lionel A. ^{[1
]}

Saudan, Christophe M. ^{[1
]}

Debieux, Catherine ^{[1
]}

Wyss, Patrick ^{[1
]}

机构：

[1] Firmenich Co, Corp R&D Div, CH-1211 Geneva 8, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 39期

关键词：

homogeneous catalysis; hydrogenation; N; P ligands; reduction; ruthenium;

D O I：

10.1002/anie.200701015

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The missing link: The presence of two N,P bridges in the ruthenium complexes used as catalysts for the title reaction is essential. Esters that contain isolated C=C bonds are reduced to the corresponding unsaturated alcohols in high yields with high chemoselectivity (see example). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7473 / 7476

页数：4

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