Hydrogenation of aldehydes, esters, imines, and ketones catalyzed by a ruthenium complex of a chiral tridentate ligand

被引：113

作者：

Clarke, Matthew L. ^{[1
]}

Diaz-Valenzuela, M. Belen ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, EaSTCHEM, St Andrews, Fife, Scotland

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 01期

关键词：

ASYMMETRIC TRANSFER HYDROGENATION; ENANTIOSELECTIVE HYDROGENATION; STEREOSELECTIVE HYDROGENATION; SELECTIVE HYDROGENATION; HYDRIDE COMPLEXES; EFFICIENT; AMINO; ACIDS;

D O I：

10.1021/om060673b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel ruthenium complex prepared from a chiral tridentate amine functionalized phosphine has been characterized by X-ray crystallography and been found to be active in the hydrogenation of an unprecedented range of CO and CN double bonds, including the enantioselective hydrogenation and transfer hydrogenation of normally unreactive bulky ketones with up to 90% ee.

引用

页码：16 / 19

页数：4

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