Hydrogen absorption by Laves phase related BCC solid solution

被引:476
作者
Akiba, E
Iba, H
机构
[1] Natl Inst Mat & Chem Res, Ibaraki 3058565, Japan
[2] Toyota Motor Co Ltd, Mat Engn Div 1, Aichi 4718572, Japan
关键词
Laves phases; multiphase intermetallics; hydrogen storage; microstructure; phase interfaces;
D O I
10.1016/S0966-9795(97)00088-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We propose a new concept of hydrogen absorbing alloy, 'Laves phase related BCC solid solution'. It was first found among the phases formed in multicomponent nominal AB(2) alloys which consisted of Zr and Ti for the A metal site and 5A, 6A and 7A transition metals for the B metal sites. In these alloys a BCC solid solution often coexisted with a Laves phase. It showed stability of hydrides and reaction kinetics almost identical to intermetallics such as Laves phase alloys. We prepared an almost pure 'Laves phase related BCC solid solution' and found that it had a large hydrogen capacity (more than 2 mass%) and fast hydrogen absorption and desorption kinetics at ambient temperature and pressure. This new hydrogen absorbing alloy may open a new era of hydrogen related application such as hydrogen vehicles. (C) 1998 Elsevier Science Limited. All rights reserved.
引用
收藏
页码:461 / 470
页数:10
相关论文
共 33 条
[1]  
AKIBA E, 1994, ELECTROCHEMICAL SOC, V94, P165
[2]   A SIMPLIFIED QUANTITATIVE APPROACH TO THE ISOTHERMAL HYSTERESIS IN METALLIC HYDRIDES WITH COHERENT INTERPHASES [J].
BARANOWSKI, B .
JOURNAL OF ALLOYS AND COMPOUNDS, 1993, 200 :87-92
[3]   EFFECT OF DISSOLVED HYDROGEN ON THE DUCTILE PROPERTIES OF METALS AS A RESULT OF NUCLEATION ON DISLOCATIONS [J].
BULBICH, AA .
JOURNAL OF ALLOYS AND COMPOUNDS, 1993, 196 (1-2) :29-36
[4]  
Enomoto E., 1992, J PHASE EQUILIB, V13, P195
[5]   THERMODYNAMIC CHARACTERIZATION OF THE ZR-MN-H SYSTEM .2. REACTION OF H-2 WITH 2-PHASE ALLOYS [J].
FLANAGAN, TB ;
NOH, H ;
LUO, W ;
OATES, WA .
JOURNAL OF ALLOYS AND COMPOUNDS, 1992, 185 (02) :339-351
[6]   X-RAY-DIFFRACTION AND H-1-NMR AND V-51-NMR STUDY OF THE TI-V-H SYSTEM [J].
HAYASHI, S ;
HAYAMIZU, K .
JOURNAL OF THE LESS-COMMON METALS, 1990, 161 (01) :61-75
[7]  
Hill RJ., 1987, POWDER DIFFR, V2, P146, DOI [DOI 10.1017/S088571560001263X, 10.1017/S088571560001263X]
[8]   CRYSTAL-STRUCTURE AND PHASE-COMPOSITION OF ALLOYS ZR1-XTIX(MN1-YVY)(2) [J].
HUOT, J ;
AKIBA, E ;
IBA, H .
JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 228 (02) :181-187
[9]   CRYSTAL-STRUCTURE, PHASE ABUNDANCE AND ELECTRODE PERFORMANCE OF LAVES PHASE-COMPOUNDS (ZR,A)V0.5NI1.1MN0.2FE0.2 (A-TI, NB OR HF) [J].
HUOT, J ;
AKIBA, E ;
OGURA, T ;
ISHIDO, Y .
JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 218 (01) :101-109
[10]   The relation between microstructure and hydrogen absorbing property in Laves phase-solid solution multiphase alloys [J].
Iba, H ;
Akiba, E .
JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 231 (1-2) :508-512