Hydrogen absorption by Laves phase related BCC solid solution

被引:476
作者
Akiba, E
Iba, H
机构
[1] Natl Inst Mat & Chem Res, Ibaraki 3058565, Japan
[2] Toyota Motor Co Ltd, Mat Engn Div 1, Aichi 4718572, Japan
关键词
Laves phases; multiphase intermetallics; hydrogen storage; microstructure; phase interfaces;
D O I
10.1016/S0966-9795(97)00088-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We propose a new concept of hydrogen absorbing alloy, 'Laves phase related BCC solid solution'. It was first found among the phases formed in multicomponent nominal AB(2) alloys which consisted of Zr and Ti for the A metal site and 5A, 6A and 7A transition metals for the B metal sites. In these alloys a BCC solid solution often coexisted with a Laves phase. It showed stability of hydrides and reaction kinetics almost identical to intermetallics such as Laves phase alloys. We prepared an almost pure 'Laves phase related BCC solid solution' and found that it had a large hydrogen capacity (more than 2 mass%) and fast hydrogen absorption and desorption kinetics at ambient temperature and pressure. This new hydrogen absorbing alloy may open a new era of hydrogen related application such as hydrogen vehicles. (C) 1998 Elsevier Science Limited. All rights reserved.
引用
收藏
页码:461 / 470
页数:10
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