Silsesquioxane chemistry:: Synthesis and structure of the novel anionic aluminosilsesquioxane [HNEt3][{Cy7Si7O9(OSiMe3)O2)}2Al]•C6H14 (Cy = c-C6H11)

被引：37

作者：

Edelmann, FT

Gun'ko, YK

Giessmann, S

Olbrich, F

Jacob, K

机构：

[1] Univ Magdeburg, Inst Chem, D-39106 Magdeburg, Germany

[2] Univ Halle Wittenberg, Inst Anorgan Chem, D-06217 Merseburg, Germany

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 02期

关键词：

D O I：

10.1021/ic9808100

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The triethylamine-assisted metathesis reaction of 2 equiv of Cy7Si7O9(OSiMe3)(OH)(2) with 1 equiv of AlCl3 affords the novel anionic aluminosilsesquioxane complex [HNEt3][{Cy7Si7O9(OSiMe3)O-2}(2)Al]. C6H14 (Cy = c-C6H11), 1, which was characterized by IR and H-1, C-13, and Si-29 NMR spectroscopy and X-ray diffraction.

引用

页码：210 / +

页数：3

共 6 条

[1] POLYHEDRAL ALUMINOSILSESQUIOXANES AS MODELS FOR ALUMINOSILICATES - UNIQUE SYNTHESIS OF ANIONIC AL/SI/O FRAMEWORKS [J].

FEHER, FJ ;

WELLER, KJ .

ORGANOMETALLICS, 1990, 9 (10) :2638-2640

[2] OXIDE-BASE ADDUCTS OF ALUMINUM - X-RAY CRYSTAL-STRUCTURES OF ME3AL(OPPH3), ME3AL(ONME3) AND [(CH3)3SIO]3AL(OPPH3) [J].

FEHER, FJ ;

BUDZICHOWSKI, TA ;

WELLER, KJ .

POLYHEDRON, 1993, 12 (06) :591-599

[3] SILASESQUIOXANES AS LIGANDS IN INORGANIC AND ORGANOMETALLIC CHEMISTRY [J].

FEHER, FJ ;

BUDZICHOWSKI, TA .

POLYHEDRON, 1995, 14 (22) :3239-3253

[4] SYNTHESIS AND CHARACTERIZATION OF AN ALUMINOSILSESQUIOXANE FRAMEWORK THAT VIOLATES LOEWENSTEIN RULE [J].

FEHER, FJ ;

WELLER, KJ ;

ZILLER, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (24) :9686-9688

[5] POLYHEDRAL ALUMINOSILSESQUIOXANES - SOLUBLE ORGANIC ANALOGS OF ALUMINOSILICATES [J].

FEHER, FJ ;

BUDZICHOWSKI, TA ;

WELLER, KJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (18) :7288-7289

[6] AL-O AND SI-O TETRAHEDRAL DISTANCES IN ALUMINOSILICATE FRAMEWORK STRUCTURES [J].

JONES, JB .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1968, B 24 :355-&

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