Metal-Organic Frameworks with Incorporated Carbon Nanotubes: Improving Carbon Dioxide and Methane Storage Capacities by Lithium Doping

被引：259

作者：

Xiang, Zhonghua ^{[1
]}

Hu, Zan ^{[1
]}

Cao, Dapeng ^{[1
]}

Yang, Wantai ^{[2
]}

Lu, Jianmin ^{[2
]}

Han, Bingyong ^{[2
]}

Wang, Wenchuan ^{[1
]}

机构：

[1] Beijing Univ Chem Technol, Div Mol & Mat Simulat, Key Lab Nanomat, Minist Educ, Beijing 100029, Peoples R China

[2] Beijing Univ Chem Technol, Coll Mat Sci & Engn, Beijing 100029, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 02期

关键词：

adsorption; doping; gas storage; metal-organic frameworks; nanotubes; HYDROGEN STORAGE; H-2; STORAGE; CO2; ADSORPTION;

D O I：

10.1002/anie.201004537

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Permanent storage: The gas storage capacities of metal-organic frameworks can be increased by incorporation of carbon nanotubes and doping of the resulting framework with lithium ions (see picture, C-turquoise, Cu-green polyhedra, Li-purple, O-red). This combination of modifications results in an improvement of the CO2 and CH4 uptakes by about 305 % and 200 % (T=298-K and P=18-bar), respectively, compared to the unmodified compounds. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：491 / 494

页数：4

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