Group 6 transition metal complexes containing the sigma-bonded 2,4,6-tris(trifluoromethyl)phenyl(''fluoromes'') ligand

被引：28

作者：

Dillon, KB

Gibson, VC

Howard, JAK

Redshaw, C

Sequeira, L

Yao, JW

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] UNIV DURHAM,DEPT CHEM,SCI LABS,DURHAM DH1 3LE,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 528卷 / 1-2期

基金：

英国工程与自然科学研究理事会;

关键词：

chromium; molybdenum; mesityl; imido; phosphine; fluorine;

D O I：

10.1016/S0022-328X(96)06700-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Group 6 transition metal complexes containing the sigma-bonded 2,4,6-tris(trifluoromethyl)phenyl (''fluoromes'' or ''fmes'') ligand are described. Treatment of CrCl2(thf) with two equivalents of Li(fmes) in the presence of PMe(3) affords divalent [Cr(PMe(3))(2)(fmes)(2)] (1), whereas reaction of Cr(N(t)Bu)(2)Cl-2 with two equivalents of Li(fmes) in diethylether gives the hexavalent bis(imido)chromium complex [Cr(N(t)Bu)(2)(fmes)(2)] (2a). The molybdenum analogue, [Mo(N(t)Bu)(2)(fmes)(2)] (2b), is obtained upon treatment of Mo(N(t)Bu)(2)Cl-2(dme) (dme = 1,2-dimethoxyethane) with Li(fmes) under similar conditions.

引用

页码：179 / 183

页数：5

共 17 条

[1] (2,4,6-tris(trifluoromethyl)phenyl)palladium(II) complexes [J].