Temperature dependence of solvation dynamics in a micelle. 4-Aminophthalimide in Triton X-100

被引：48

作者：

Sen, P ^{[1
]}

Mukherjee, S ^{[1
]}

Haider, A ^{[1
]}

Bhattacharyya, K ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Phys Chem Dept, Kolkata 700032, W Bengal, India

来源：

CHEMICAL PHYSICS LETTERS | 2004年 / 385卷 / 5-6期

关键词：

D O I：

10.1016/j.cplett.2003.12.115

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Solvation dynamics of 4-aminophthalimide (4-AP) is studied in a Triton X-100 (TX) micelle at three different temperatures. The average solvation time <tau(s)> has been found to be 800, 400 and 110 ps at 283, 303 and 323 K, respectively. This corresponds to an activation energy of 9 +/- 1 kcal mol(-1). The observed temperature dependence is in qualitative agreement with recent computer simulations on the solvation dynamics in micelles. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：357 / 361

页数：5

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