Strong optical limiting (OL) capability of the two-dimensional network cluster polymer [MoS4Cu6I4(py)4]n

被引:76
作者
Hou, HW [1 ]
Fan, YT
Du, CX
Zhu, Y
Wang, WL
Xin, XQ
Low, MKM
Ji, W
Ang, HG
机构
[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Henan, Peoples R China
[2] Nanjing Univ, Dept Chem, Nanjing 210093, Peoples R China
[3] Natl Univ Singapore, Dept Phys, Singapore 119260, Singapore
[4] Natl Univ Singapore, Dept Chem, Singapore 119260, Singapore
关键词
D O I
10.1039/a900518h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The two-dimensional network compound [MoS4Cu6I4-(py)(4)](n) is the first example of a cluster polymer showing very large optical limiting effects; its nonlinear absorptive index alpha(2) and nonlinear refractive value n(2) are 1.5 x 10(-9) m W-1 and -2.5 x 10(-17) m(2) W-1, respectively, in 6.5 x 10(-5) mol dm(-3) DMSO solution; the optical limiting threshold was determined to be 0.6 J cm(-2), which is about three times better than that of C-60.
引用
收藏
页码:647 / 648
页数:2
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