Bulk and interface properties of molybdenum trioxide-doped hole transporting layer in organic light-emitting diodes

被引:93
作者
Shin, Won-Ju [1 ]
Lee, Je-Yun [1 ]
Kim, Jae Chang [1 ]
Yoon, Tae-Hoon [1 ]
Kim, Tae-Shick [2 ]
Song, Ok-Keun [2 ]
机构
[1] Pusan Natl Univ, Sch Elect Engn, Pusan 609735, South Korea
[2] Samsung SDI, R&D Ctr, Yongin 449577, Gyeonggi Do, South Korea
关键词
OLED; metal oxide; charge transfer complex; interface; stability;
D O I
10.1016/j.orgel.2007.12.001
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Effects of doping molybdenum trioxide (MoO3) in N,N'-diphenyl-N,N'-bis(1,1'-biphenyl)-4,4'-diamine (NPB) are studied at various thicknesses of doped layer (25-500 angstrom) by measuring the current-voltage characteristics, the capacitance-voltage characteristics and the operating lifetime. We formed charge transfer complex of NPB and MoO3 by co-evaporation of both materials to achieve higher charge density, lower operating voltage, and better reliability of devices. These improved performances may be attributed to both bulk and interface properties of the doped layer. The authors demonstrated that the interface effects play more important role in lowering the operating voltage and increasing the lifetime. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:333 / 338
页数:6
相关论文
共 24 条
[1]   Degradation mechanism of small molecule-based organic light-emitting devices [J].
Aziz, H ;
Popovic, ZD ;
Hu, NX ;
Hor, AM ;
Xu, G .
SCIENCE, 1999, 283 (5409) :1900-1902
[2]   Improved performance of the single-layer and double-layer organic light emitting diodes by nickel oxide coated indium tin oxide anode [J].
Chan, IM ;
Hong, FC .
THIN SOLID FILMS, 2004, 450 (02) :304-311
[3]   Real-time three-dimensional surface measurement by color encoded light projection [J].
Chen, S. Y. ;
Li, Y. F. ;
Guan, Q. ;
Xiao, G. .
APPLIED PHYSICS LETTERS, 2006, 89 (11)
[4]   Integration of organic light-emitting diode and organic transistor via a tandem structure [J].
Chu, CW ;
Chen, CW ;
Li, SH ;
Wu, EHE ;
Yang, Y .
APPLIED PHYSICS LETTERS, 2005, 86 (25) :1-3
[5]   Organic electroluminescent devices with a vacuum-deposited Lewis-acid-doped hole-injecting layer [J].
Endo, J ;
Matsumoto, T ;
Kido, J .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2002, 41 (3B) :L358-L360
[6]   Improved drive voltages of organic electroluminescent devices with an efficient p-type aromatic diamine hole-injection layer [J].
Ganzorig, C ;
Fujihira, M .
APPLIED PHYSICS LETTERS, 2000, 77 (25) :4211-4213
[7]   Fine tuning work function of indium tin oxide by surface molecular design: Enhanced hole injection in organic electroluminescent devices [J].
Ganzorig, C ;
Kwak, KJ ;
Yagi, K ;
Fujihira, M .
APPLIED PHYSICS LETTERS, 2001, 79 (02) :272-274
[8]   Controlled p-doping of zinc phthalocyanine by coevaporation with tetrafluorotetracyanoquinodimethane:: A direct and inverse photoemission study [J].
Gao, WY ;
Kahn, A .
APPLIED PHYSICS LETTERS, 2001, 79 (24) :4040-4042
[9]   High-efficiency and low-voltage p-i-n electrophosphorescent organic light-emitting diodes with double-emission layers [J].
He, GF ;
Pfeiffer, M ;
Leo, K ;
Hofmann, M ;
Birnstock, J ;
Pudzich, R ;
Salbeck, J .
APPLIED PHYSICS LETTERS, 2004, 85 (17) :3911-3913
[10]   Effective hole injection of organic light-emitting diodes by introducing buckminsterfullerene on the indium tin oxide anode [J].
Hong, IH ;
Lee, MW ;
Koo, YM ;
Jeong, H ;
Kim, TS ;
Song, OK .
APPLIED PHYSICS LETTERS, 2005, 87 (06)