Toward the Ideal Catalyst: From Atomic Centers to a "Cocktail" of Catalysts

被引：260

作者：

Ananikov, Valentine P. ^{[1
]}

Beletskaya, Irina P. ^{[2
]}

机构：

[1] Russian Acad Sci, Zelinsky Inst Organ Chem, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

ORGANOMETALLICS | 2012年 / 31卷 / 05期

关键词：

SUZUKI-MIYAURA REACTION; HETEROGENEOUS PALLADIUM CATALYSTS; SOLVENT-FREE CONDITIONS; H BOND ADDITION; COUPLING REACTIONS; HECK REACTION; ORGANIC-SYNTHESIS; NONCONVENTIONAL METHODOLOGIES; HOMOGENEOUS CATALYSIS; ALKYNE INSERTION;

D O I：

10.1021/om201120n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The current state of the art and perspectives of homogeneous and heterogeneous catalysis are discussed for C-C and C-heteroatom bond formation in organic synthesis. The relationship between catalyst centers represented by a single metal atom and by multiple metal atoms is considered for reactions taking place in solution. The influence of leaching and catalyst evolution in the liquid phase on the activity, selectivity, and stability of the catalyst is highlighted from a mechanistic point of view. Metal nanoparticle and "nanosalt" types of catalysts are compared for constructing new C-C and C-heteroatom bonds.

引用

页码：1595 / 1604

页数：10

共 124 条

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