Toward the Ideal Catalyst: From Atomic Centers to a "Cocktail" of Catalysts

被引：260

作者：

Ananikov, Valentine P. ^{[1
]}

Beletskaya, Irina P. ^{[2
]}

机构：

[1] Russian Acad Sci, Zelinsky Inst Organ Chem, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

ORGANOMETALLICS | 2012年 / 31卷 / 05期

关键词：

SUZUKI-MIYAURA REACTION; HETEROGENEOUS PALLADIUM CATALYSTS; SOLVENT-FREE CONDITIONS; H BOND ADDITION; COUPLING REACTIONS; HECK REACTION; ORGANIC-SYNTHESIS; NONCONVENTIONAL METHODOLOGIES; HOMOGENEOUS CATALYSIS; ALKYNE INSERTION;

D O I：

10.1021/om201120n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The current state of the art and perspectives of homogeneous and heterogeneous catalysis are discussed for C-C and C-heteroatom bond formation in organic synthesis. The relationship between catalyst centers represented by a single metal atom and by multiple metal atoms is considered for reactions taking place in solution. The influence of leaching and catalyst evolution in the liquid phase on the activity, selectivity, and stability of the catalyst is highlighted from a mechanistic point of view. Metal nanoparticle and "nanosalt" types of catalysts are compared for constructing new C-C and C-heteroatom bonds.

引用

页码：1595 / 1604

页数：10

共 124 条

[41] Kinetics and mechanistic aspects of the Heck reaction promoted by a CN-palladacycle [J].

Consorti, CS ;

Flores, FR ;

Dupont, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (34) :12054-12065

[42] Homogeneous and heterogeneous catalysis:: Bridging the gap through surface organometallic chemistry [J].

Copéret, C ;

Chabanas, M ;

Saint-Arroman, RP ;

Basset, JM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (02) :156-181

[43] Recent developments in the addition of phosphinylidene-containing compounds to unactivated unsaturated hydrocarbons: Phosphorus-carbon bond formation by hydrophosphinylation and related processes [J].

Coudray, Laetitia ;

Montchamp, Jean-Luc .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 2008 (21) :3601-3613

[44] A unifying mechanism for all high-temperature Heck reactions. The role of palladium colloids and anionic species [J].

de Vries, JG .

DALTON TRANSACTIONS, 2006, (03) :421-429

[45] Hydrophosphination of unactivated alkenes, dienes and alkynes: A versatile and valuable approach for the synthesis of phosphines [J].

Delacroix, O ;

Gaumont, AC .

CURRENT ORGANIC CHEMISTRY, 2005, 9 (18) :1851-1882

[46] Review on Modern Advances of Chemical Methods for the Introduction of a Phosphonic Acid Group [J].

Demmer, Charles S. ;

Krogsgaard-Larsen, Niels ;

Bunch, Lennart .

CHEMICAL REVIEWS, 2011, 111 (12) :7981-8006

[47] Ring opening of 1,3-dimethylcyclohexane on Ir catalysts Modification of product distribution by addition of Ni and K to improve fuel properties [J].

Dokjampa, Siraprapha ;

Rirksomboon, Thirasak ;

Phuong, Do T. M. ;

Resasco, Daniel E. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 274 (1-2) :231-240

[48] An overview of palladium nanocatalysts:: Surface and molecular reactivity [J].

Durand, Jerome ;

Teuma, Emmanuelle ;

Gomez, Montserrat .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (23) :3577-3586

[49] Implication of palladium geometric and electronic structures to hydrogen activation on bulk surfaces and clusters [J].

Efremenko, I .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 173 (1-2) :19-59

[50] Evidence for the Surface-Catalyzed Suzuki-Miyaura Reaction over Palladium Nanoparticles: An Operando XAS Study [J].

Ellis, Peter J. ;

Fairlamb, Ian J. S. ;

Hackett, Simon F. J. ;

Wilson, Karen ;

Lee, Adam F. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (10) :1820-1824

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