Experimental study of the 61Π and 71Π states of NaK by polarization labeling spectroscopy technique

被引：21

作者：

Grochola, A

Jastrzebski, W

Kortyka, P

Kowalczyk, P

机构：

[1] Univ Warsaw, Inst Expt Phys, PL-00681 Warsaw, Poland

[2] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 2003年 / 221卷 / 02期

关键词：

diatomic molecules; electronic states; laser spectroscopy;

D O I：

10.1016/S0022-2852(03)00233-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The polarization labeling spectroscopy technique is used to study the 6(1)Pi <-- X(1)Sigma(+) and 7(1)Pi <-- X(1)Sigma(+) band systems of the NaK molecule located in the UV range. For both excited states accurate molecular constants are derived which describe the 6(1)Pi state to 68% and the 7(1)Pi state to 71% of their potential well depths. The parameters deduced from the experiment are compared with the recent theoretical calculations. (C) 2003 Elsevier Inc. All rights reserved.

引用

页码：279 / 284

页数：6

共 19 条

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[2]

BARROW RF, 1992, ANNU REP PROG CHEM C, V89, P353

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