Genesis, architecture and nature of sites of Co(Ni)-MoS2 supported hydroprocessing catalysts

被引:48
作者
Grimblot, J [1 ]
机构
[1] Univ Sci & Tech Lille Flandres Artois, URA CNRS 402, Catalyse Heterogene & Homogene Lab, F-59655 Villeneuve Dascq, France
关键词
hydroprocessing catalysis; molybdate impregnation; Co or Ni ion impregnation; MoS2; promoter effect; active sites;
D O I
10.1016/S0920-5861(98)00042-X
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The present paper examines some features relevant to hydroprocessing reactions over MoS2 supported catalysts promoted by Co or Ni. After the description of the main classes of reactions, catalyst genesis and activation (i.e. sulphidation) are extensively described and discussed. The final part deals with the identification of the catalyst active sites, the role of the promoters and also presents some mechanistic considerations. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
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页码:111 / 128
页数:18
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