Genesis, architecture and nature of sites of Co(Ni)-MoS2 supported hydroprocessing catalysts

被引：48

作者：

Grimblot, J ^{[1
]}

机构：

[1] Univ Sci & Tech Lille Flandres Artois, URA CNRS 402, Catalyse Heterogene & Homogene Lab, F-59655 Villeneuve Dascq, France

来源：

CATALYSIS TODAY | 1998年 / 41卷 / 1-3期

关键词：

hydroprocessing catalysis; molybdate impregnation; Co or Ni ion impregnation; MoS2; promoter effect; active sites;

D O I：

10.1016/S0920-5861(98)00042-X

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The present paper examines some features relevant to hydroprocessing reactions over MoS2 supported catalysts promoted by Co or Ni. After the description of the main classes of reactions, catalyst genesis and activation (i.e. sulphidation) are extensively described and discussed. The final part deals with the identification of the catalyst active sites, the role of the promoters and also presents some mechanistic considerations. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：111 / 128

页数：18

共 88 条

[31] TEM LATTICE IMAGING OF THE NANOSTRUCTURE OF EARLY-GROWTH SPUTTER-DEPOSITED MOS2 SOLID LUBRICANT FILMS [J].

HILTON, MR ;

FLEISCHAUER, PD .

JOURNAL OF MATERIALS RESEARCH, 1990, 5 (02) :406-421

[32] NATURE OF THE DIFFERENT NICKEL SPECIES IN SULFIDED BULK AND ALUMINA-SUPPORTED NIMO HYDROTREATING CATALYSTS [J].

HOUSSENBAY, S ;

KASZTELAN, S ;

TOULHOAT, H ;

BONNELLE, JP ;

GRIMBLOT, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (20) :7176-7180

[33] HDM OF THE VANADYL OCTAETHYLPORPHYRIN ON MOS2-BASED CATALYSTS - NATURE AND REPARTITION OF THE VANADIUM DEPOSIT [J].

HUBAUT, R ;

DEJONGHE, S ;

GRIMBLOT, J ;

BONNELLE, JP .

REACTION KINETICS AND CATALYSIS LETTERS, 1993, 51 (01) :9-17

[34] HYDROGENATION OF OLEFINS ON A MOS2/GAMMA-AL2O3 CATALYST - ROLE OF P, F AND ALKALINE CATION ADDITIVES [J].

HUBAUT, R ;

POULET, O ;

KASZTELAN, S ;

GRIMBLOT, J .

JOURNAL OF MOLECULAR CATALYSIS, 1993, 81 (02) :301-310

[35] QUANTITATIVE DETECTION OF REACTIVE HYDROGEN ON MOS2/GAMMA-AL2O3 AND ON GAMMA-AL2O3 [J].

JALOWIECKI, L ;

GRIMBLOT, J ;

BONNELLE, JP .

JOURNAL OF CATALYSIS, 1990, 126 (01) :101-108

[36] EFFECT OF MO LOADING OF MOS2/GAMMA-AL2O3 ON DIENE HYDROGENATION - EVIDENCE OF AN ELEMENTARY ENSEMBLE SITE [J].

JALOWIECKIDUHAMEL, L ;

GRIMBLOT, J ;

BONNELLE, JP .

JOURNAL OF CATALYSIS, 1991, 129 (02) :511-518

[37] LOW-ENERGY ION-SCATTERING STUDY OF NI-MO-AL2O3 CATALYSTS [J].

JEZIOROWSKI, H ;

KNOZINGER, H ;

TAGLAUER, E ;

VOGDT, C .

JOURNAL OF CATALYSIS, 1983, 80 (02) :286-295

[38] RAMAN AND ULTRAVIOLET SPECTROSCOPIC CHARACTERIZATION OF MOLYBDENA ON ALUMINA CATALYSTS [J].

JEZIOROWSKI, H ;

KNOZINGER, H .

JOURNAL OF PHYSICAL CHEMISTRY, 1979, 83 (09) :1166-1173

[39] INDUSTRIAL MOO3-PROMOTER OXIDE GAMMA-AL2O3 HYDROTREATING CATALYSTS - GENESIS AND ARCHITECTURE DESCRIPTION [J].

KASZTELAN, S ;

PAYEN, E ;

TOULHOAT, H ;

GRIMBLOT, J ;

BONNELLE, JP .

POLYHEDRON, 1986, 5 (1-2) :157-167

[40] SURFACE-ANALYSIS OF ALUMINA-SUPPORTED MOO3, NIO, AND NIO-MOO3 BY LOW-ENERGY ION-SCATTERING SPECTROSCOPY [J].

KASZTELAN, S ;

GRIMBLOT, J ;

BONNELLE, JP .

JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (06) :1503-1508

← 1 2 3 4 5 6 7 8 9 →