Non-stoichiometric GaAsBi/GaAs (100) molecular beam epitaxy growth

被引:48
作者
Bastiman, F. [1 ]
Mohmad, A. R. B. [1 ,2 ]
Ng, J. S. [1 ]
David, J. P. R. [1 ]
Sweeney, S. J. [3 ,4 ]
机构
[1] Univ Sheffield, Dept Elect & Elect Engn, Sheffield S1 3JD, S Yorkshire, England
[2] Natl Univ Malaysia, Inst Microengn & Nanoelect, Bangi 43000, Selangor, Malaysia
[3] Univ Surrey, Dept Phys, Guildford GU2 7XH, Surrey, England
[4] Univ Surrey, Adv Technol Inst, Guildford GU2 7XH, Surrey, England
基金
英国工程与自然科学研究理事会;
关键词
Scanning tunnelling microscopy; Molecular beam epitaxy; Bismuth; Semiconductor III-V materials; INTERACTION KINETICS; BAND-GAP; GAAS(001);
D O I
10.1016/j.jcrysgro.2011.07.036
中图分类号
O7 [晶体学];
学科分类号
070301 [无机化学];
摘要
The growth of III-V bismuthides is complicated by the low incorporation efficiency of Bi in GaAs, leading either to the formation of metallic Bi droplets or low layer composition fractions. Typically growth is performed between 280 and 350 degrees C and at near stoichiometric Ga:As fluxes in order to encourage Bi incorporation. However most work reported to date also utilises As-2 as the As overpressure constituent. It is found in this work that growth with As-4 allows high Bi composition films with the standard 1:20 Ga:As-4 beam equivalent pressure ratio (BEPR) utilised for higher temperature buffer layer growth. The Bi fraction versus Bi:As-4 BEPR is found to be initially linear, until a maximum value is obtained for a given temperature after which the continued oversupply of Bi results in the formation of droplets. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:57 / 61
页数:5
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