Sonochemical preparation and characterization of nanocrystalline copper oxide embedded in poly(vinyl alcohol) and its effect on crystal growth of copper oxide

被引:283
作者
Kumar, RV
Elgamiel, R
Diamant, Y
Gedanken, A [1 ]
Norwig, J
机构
[1] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel
[2] Max Planck Inst Polymer Res, D-55021 Mainz, Germany
关键词
D O I
10.1021/la001331s
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Uniformly dispersed copper oxide nanoparticles in poly(vinyl alcohol) (CuO-PVA) have been synthesized by the sonochemical method. The properties of the as-prepared composite material are characterized by XRD, DSC, thermogravimetric analysis (TGA), TEM, and diffuse reflection spectroscopy (DRS). A band gap of 2.1 eV is estimated from DRS measurements. The controlled crystal growth of copper oxide has been studied by using the as-prepared CuO-PVA composite as seed for the crystal growth of copper oxide. Well-shaped crystals of 1 mum in length were grown.
引用
收藏
页码:1406 / 1410
页数:5
相关论文
共 53 条
[1]  
Antonietti M, 1998, CHEM-EUR J, V4, P2493, DOI 10.1002/(SICI)1521-3765(19981204)4:12<2493::AID-CHEM2493>3.0.CO
[2]  
2-V
[3]   PRESENT LIMITS OF DATA-STORAGE USING DYE MOLECULES IN SOLID MATRICES [J].
AO, R ;
KUMMERL, L ;
HAARER, D .
ADVANCED MATERIALS, 1995, 7 (05) :495-&
[4]   Sonochemical hydrolysis of Ga3+ ions:: Synthesis of scroll-like cylindrical nanoparticles of gallium oxide hydroxide [J].
Avivi, S ;
Mastai, Y ;
Hodes, G ;
Gedanken, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (17) :4196-4199
[5]   ALUMINUM HYDROUS OXIDE SOLS .1. SPHERICAL-PARTICLES OF NARROW SIZE DISTRIBUTION [J].
BRACE, R ;
MATIJEVI.E .
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1973, 35 (11) :3691-3705
[6]  
Bradley FN, 1976, MAT MAGNETIC FUNCTIO
[7]  
BRETT MJ, 1985, SOLID STATE COMMUN, V603
[8]   Control of CuO particle size on SiO2 by spin coating [J].
Brookshier, MA ;
Chusuei, CC ;
Goodman, DW .
LANGMUIR, 1999, 15 (06) :2043-2046
[9]   HIGHLY EFFICIENT HETEROGENEOUS PHOTOOXIDATION OF 2-PROPANOL TO ACETONE WITH AMORPHOUS MANGANESE OXIDE CATALYSTS [J].
CAO, H ;
SUIB, SL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (12) :5334-5342
[10]  
Clay RT, 1998, NEW J CHEM, V22, P745