The simultaneous removal of calcium and chloride ions from calcium chloride solution using magnesium-aluminum oxide

被引:66
作者
Kameda, T
Yoshioka, T
Mitsuhashi, T
Uchida, M
Okuwaki, A
机构
[1] Tohoku Univ, Inst Multidisciplinary Res Adv Mat, Aoba Ku, Sendai, Miyagi 9808577, Japan
[2] Tohoku Univ, Grad Sch Engn, Dept Appl Chem, Aoba Ku, Sendai, Miyagi 9808579, Japan
关键词
hydrotalcite-like compound; magnesium-aluminum oxide; CaCl2; solution; removal; simultaneous; buffering action;
D O I
10.1016/S0043-1354(03)00311-7
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
We investigated the removal of Ca2+ and Cl- from CaCl2 solution at 20-60degreesC, using magnesium-aluminum oxide, Me0.80Al0.20O1.10, prepared by the thermal decomposition of a hydrotalcite-like compound, Mg0.80Al0.20(OH)(2) (CO3)(0.10) (.) 0.78H(2)O. The degree of Ca2+ and Cl- removal from the solution increased with increasing initial CaCl2 concentration. temperature, and quantity of Mg0.80Al0.20O1.10 added. When Mg0.80Al0.20O1.10 was added to 0.25 M CaCl2 solution in a Mg0.80Al0.20O1.10/CaCl2 molar ratio of 20, the degree of Ca2+ and Cl- removal from the solution at 60degreesC after 0.5h was 93.0% and 98.2%, respectively. These results reveal that Mg0.80Al0.20O1.10 has the capacity to remove Ca2+ and Cl- simultaneously from aqueous solution. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4045 / 4050
页数:6
相关论文
共 23 条
[1]   HYDROTALCITE-TYPE ANIONIC CLAYS: PREPARATION, PROPERTIES AND APPLICATIONS [J].
Cavani, F. ;
Trifiro, F. ;
Vaccari, A. .
CATALYSIS TODAY, 1991, 11 (02) :173-301
[2]   BASIC PROPERTIES OF MG1-X(2+)ALX(3+) LAYERED DOUBLE HYDROXIDES INTERCALATED BY CARBONATE, HYDROXIDE CHLORIDE AND SULFATE ANIONS [J].
CONSTANTINO, VRL ;
PINNAVAIA, TJ .
INORGANIC CHEMISTRY, 1995, 34 (04) :883-892
[3]  
HORII Y, 1997, HAIKIBUTSUGAKKAISHI, V8, P529
[4]   CRYSTAL STRUCTURES OF SJOGRENITE AND PYROAURITE [J].
INGRAM, L ;
TAYLOR, HFW .
MINERALOGICAL MAGAZINE AND JOURNAL OF THE MINERALOGICAL SOCIETY, 1967, 36 (280) :465-&
[5]   New treatment methods for waste water containing chloride ion using magnesium-aluminum oxide [J].
Kameda, T ;
Miyano, Y ;
Yoshioka, T ;
Uchida, M ;
Okuwaki, A .
CHEMISTRY LETTERS, 2000, (10) :1136-1137
[6]   New method of treating dilute mineral acids using magnesium-aluminum oxide [J].
Kameda, T ;
Yabuuchi, F ;
Yoshioka, T ;
Uchida, M ;
Okuwaki, A .
WATER RESEARCH, 2003, 37 (07) :1545-1550
[7]   Synthesis of hydrotalcite from seawater and its application to phosphorus removal [J].
Kameda, T ;
Yoshioka, T ;
Uchida, M ;
Okuwaki, A .
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2002, 177 (6-7) :1503-1506
[8]   New treatment method for dilute hydrochloric acid using magnesium-aluminum oxide [J].
Kameda, T ;
Yoshioka, T ;
Uchida, M ;
Miyano, Y ;
Okuwaki, A .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2002, 75 (03) :595-599
[9]  
KAWAMOTO A, 1999, MIZUKANNKYOUGAKKAISH, V22, P875
[10]   ANION-EXCHANGE PROPERTIES OF HYDROTALCITE-LIKE COMPOUNDS [J].
MIYATA, S .
CLAYS AND CLAY MINERALS, 1983, 31 (04) :305-311