Nitration of N-confused porphyrin

被引:69
作者
Ishikawa, Y
Yoshida, I
Akaiwa, K
Koguchi, E
Sasaki, T
Furuta, H
机构
[1] Department of Applied Chemistry, Oita University, Oita Dannoharu 700
关键词
ISOMER; RING;
D O I
10.1246/cl.1997.453
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The internal carbon of the inverted pyrrole in N-confused tetraphenylporphyrin 1 (5,10,15,20-tetraphenyl-2-aza-21-carbaporphyrin) was nitrated by using the following aqueous solutions at room temperature for several minutes; (1) NaNO2/HCl (yield 71%) and (2) 30 wt% nitric acid (yield 27%).
引用
收藏
页码:453 / 454
页数:2
相关论文
共 9 条