Kinetic transition in excited-state reversible reactions

被引：37

作者：

Agmon, N ^{[1
]}

Gopich, IV

机构：

[1] Hebrew Univ Jerusalem, Fritz Haber Res Ctr, Dept Phys Chem, IL-91904 Jerusalem, Israel

[2] Russian Acad Sci, Inst Chem Kinet & Combust, Novosibirsk 630090, Russia

来源：

CHEMICAL PHYSICS LETTERS | 1999年 / 302卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(99)00168-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We demonstrate that reversible reactions occurring in the excited electronic state undergo a 'kinetic transition' as a function of the difference in excited-state decay rates. This conclusion follows from a remarkably accurate approximate solution obtained for the kinetics of diffusion-influenced reversible geminate dissociation reactions in solution, which becomes exact at long times. (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：399 / 404

页数：6

共 25 条

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