The synthesis and coordination chemistry of 2,6-bis(pyrazolyl)pyridines and related ligands - Versatile terpyridine analogues

被引：311

作者：

Halcrow, MA ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

来源：

COORDINATION CHEMISTRY REVIEWS | 2005年 / 249卷 / 24期

关键词：

tridentate ligands; synthesis; lanthanide complexes; spin-crossover;

D O I：

10.1016/j.ccr.2005.03.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Derivatives of 2,6-di(pyrazol-1-yl)pyridine and 2,6-di(pyrazol-3-yl)pyridine have been used as ligands for 15 years, and have both advantages and disadvantages in this regard compared to the much more widely investigated terpyridines. A review of the synthesis of these and some related ligand types, and a survey of their complex chemistry, are presented. Highlights of the latter include luminescent lanthanide compounds for biological sensing, and iron complexes showing unusual thermal and photochemical spin-state transitions. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：2880 / 2908

页数：29

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