Synthesis of 3-silyl-2(5H)-furanone by rhodium-catalyzed cyclocarbonylation

被引：18

作者：

Fukuta, Y ^{[1
]}

Matsuda, I ^{[1
]}

Itoh, K ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Mol Design & Engn, Nagoya, Aichi 4648603, Japan

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 07期

关键词：

cyclocarbonylation; rhodium complex; synthesis gas; 2(5H)-furanone;

D O I：

10.1016/S0040-4039(00)02234-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3-Silyl-2(5H)-furanones are readily formed by the rhodium-catalyzed cyclocarbonylation of propargyl alcohol derivatives bearing a trialkylsilyl group on the terminal sp-carbon under hydroformylation conditions. The following two requirements must he satisfied for the success of this protocol; (i) the presence of a silyl group on the sp-carbon, and (ii) the presence of a catalytic amount of Rh-4(CO)(12). (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1301 / 1304

页数：4

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