RHODIUM-CATALYZED HYDROFORMYLATION OF INTERNAL ALKYNES TO ALPHA,BETA-UNSATURATED ALDEHYDES

被引：67

作者：

JOHNSON, JR ^{[1
]}

CUNY, GD ^{[1
]}

BUCHWALD, SL ^{[1
]}

机构：

[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 16期

关键词：

ALKENES; ALKYNES; CATALYSIS; HYDROFORMYLATION; RHODIUM COMPOUNDS;

D O I：

10.1002/anie.199517601

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Under mild conditions—1 atm syngas and room temperature—symmetric internal alkynes are selectively converted into α,β‐unsaturated aldehydes in good yields [Eq. (a)]. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：1760 / 1761

页数：2

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