HIGHLY EFFICIENT REGIOSELECTIVE SILYLCARBONYLATION OF ALKYNES CATALYZED BY DIRHODIUM(II) PERFLUOROBUTYRATE

被引：50

作者：

DOYLE, MP

SHANKLIN, MS

机构：

[1] Department of Chemistry, Trinity University, San Antonio

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 01期

关键词：

D O I：

10.1021/om00025a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rhodium(II) perfluorobutyrate is an effective catalyst for silylcarbonylation of terminal acetylenes in reactions performed at atmospheric pressure and at or below room temperature. Beta-Silylacrylaldehydes are formed with exceptional stereocontrol for the Z isomer, which can be isomerized to the E isomer under mild conditions.

引用

页码：11 / 12

页数：2

共 15 条

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