REGIOSELECTIVE INCORPORATION OF CO INTO ENAMINES BY RHODIUM-CATALYZED REACTION WITH A HYDROSILANE AND CO

被引：32

作者：

IKEDA, S ^{[1
]}

CHATANI, N ^{[1
]}

KAJIKAWA, Y ^{[1
]}

OHE, K ^{[1
]}

MURAI, S ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 01期

关键词：

D O I：

10.1021/jo00027a002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of [RhCl(CO)2]2, the reaction of enamines with a hydrosilane and carbon monoxide (140-degrees-C, 50 atm of CO) resulted in regioselective incorporation of CO into the alpha-carbon atom to give alpha-(siloxymethylene) amines, which can be easily converted into alpha-siloxy ketones by hydrolysis.

引用

页码：2 / 4

页数：3

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