Heteroaryi-substituted C3-bridged oligopyrroles:: Potential building subunits of anion-responsive π-conjugated oligomers

被引:67
作者
Maeda, Hiromitsu [1 ,2 ]
Mihashi, Yuta [1 ]
Haketa, Yohei [1 ]
机构
[1] Ritsumeikan Univ, Inst Sci & Engn, Coll Pharmaceut Sci, Kusatsu 5258577, Japan
[2] Japan Sci & Technol Agcy, PRESTO, Kawaguchi, Saitama 3320012, Japan
关键词
D O I
10.1021/ol801014z
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Acyclic anion receptors (BF2 complexes of dipyrrolyidiketones) with heteroaryl moieties synthesized by using cross-coupling reactions have unique electronic states, as observed in UV/vis absorption spectra. Among heteroaryl-substituted derivatives, a pyrrolyl-substituted receptor exhibits an extremely high affinity for anions in solution.
引用
收藏
页码:3179 / 3182
页数:4
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共 36 条
[21]   BF2 complex of fluorinated dipyrrolyldiketone:: A new class of efficient receptor for acetate anions [J].
Maeda, Hiromitsu ;
Ito, Yoshihiro .
INORGANIC CHEMISTRY, 2006, 45 (20) :8205-8210
[22]   Fluorogenic and chromogenic chemosensors and reagents for anions [J].
Martínez-Máñez, R ;
Sancenón, F .
CHEMICAL REVIEWS, 2003, 103 (11) :4419-4476
[23]   Phenanthroline complexes bearing fused dipyrrolylquinoxaline anion recognition sites: Efficient fluoride anion receptors. [J].
Mizuno, T ;
Wei, WH ;
Eller, LR ;
Sessler, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (07) :1134-1135
[24]   The size-selective synthesis of folded oligomers by dynamic templation [J].
Nishinaga, T ;
Tanatani, A ;
Oh, KC ;
Moore, JS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (21) :5934-5935
[25]   Assisted formation of chiral porphyrin homoaggregates by an induced helical poly(phenylacetylene) template and their chiral memory [J].
Onouchi, H ;
Miyagawa, T ;
Morino, K ;
Yashima, E .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (15) :2381-2384
[26]   Dipyrrolyl-functionalized bipyridine-based anion receptors for emission-based selective detection of dihydrogen phosphate [J].
Plitt, Patrick ;
Gross, Dustin E. ;
Lynch, Vincent M. ;
Sessler, Jonathan L. .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (05) :1374-1381
[27]   Sensitivity gains in chemosensing by lasing action in organic polymers [J].
Rose, A ;
Zhu, ZG ;
Madigan, CF ;
Swager, TM ;
Bulovic, V .
NATURE, 2005, 434 (7035) :876-879
[28]   Artificial organic host molecules for anions [J].
Schmidtchen, FP ;
Berger, M .
CHEMICAL REVIEWS, 1997, 97 (05) :1609-1646
[29]   Synthesis and anion binding properties of N,N'-bispyrrol-2-yl-2,5-diamidopyrrole [J].
Sessler, JL ;
Pantos, GD ;
Gale, PA ;
Light, ME .
ORGANIC LETTERS, 2006, 8 (08) :1593-1596
[30]   Quinoxaline-oligopyrroles: Improved pyrrole-based anion receptors [J].
Sessler, JL ;
Maeda, H ;
Mizuno, T ;
Lynch, VM ;
Furuta, H .
CHEMICAL COMMUNICATIONS, 2002, (08) :862-863