A solvothermal route to CdS nanocrystals

被引：42

作者：

Gautam, UK ^{[1
]}

Seshadri, R ^{[1
]}

Rao, CNR ^{[1
]}

机构：

[1] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 375卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(03)00912-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel solvothermal route for the preparation of organic soluble CdS nanocrystals, involving the reaction of cadmium stearate with sulfur in the presence of tetralin has been described. Tetralin in the presence of S gives H2S, getting aromatized to naphthalene. By using trioctylphosphmeoxide as the capping agent, nanocrystals of 4 nm are obtained. Use of dodecanethiol cap results in 5 nm as well as 10 nm nanocrystals which can be separated readily. The nanocrystals have the cubic zinc blende structure and exhibit blue shifts of the absorption maximum. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：560 / 564

页数：5

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