Glassy carbon electrodes modified with single walled carbon nanotubes and cobalt phthalocyanine and nickel tetrasulfonated phthalocyanine: Highly stable new hybrids with enhanced electrocatalytic performances

被引：67

作者：

Silva, J. Francisco

Griveau, Sophie

Richard, Cyrille

Zagal, Jose H.

Bedioui, Fethi ^{[1
]}

机构：

[1] CNRS, INSERM, UMR 8151, U640, F-75700 Paris, France

[2] Univ Paris 05, Fac Pharm, Ecole Natl Super Chim Paris, Chem & Genet Pharmacol Lab, Paris, France

[3] Univ Santiago Chile, Fac Quim & Biol, Dept Quim Mat, Santiago, Chile

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2007年 / 9卷 / 07期

关键词：

single walled carbon nanotube; cobalt phthalocyanine; nickel tetrasulfonated phthalocyanine; electrocatalysis; 2-mercaptoethanol; nitric oxide;

D O I：

10.1016/j.elecom.2007.03.008

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

We report here a fast procedure to modify glassy carbon (GC) electrode using commercially available unsubstituted cobalt phthalocyanine (COPC) and tetrasulfonated substituted nickel phthalocyanine (NiTSPc) simply adsorbed on oxidized single walled carbon nanotubes SWCNT. The electrocatalytic activity of the resulting SWCNT-MPc nanocomposite materials was evaluated toward the oxidation of two biologically relevant molecules, namely 2-mercaptoethanol (2-ME) and nitric oxide (NO). The obtained electrodes are highly stable under hydrodynamic conditions and the tailored hybrid surfaces allow enhancing electron transfer for the electrocatalytic oxidation of 2-ME and NO. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：1629 / 1634

页数：6

共 40 条

[1] Chemically functionalized carbon nanotubes [J].